Synthesis of a carborane-substituted bis(phosphanido) cobaltate(i), ligand substitution, and unusual P4 fragmentation-Reference-Cited by-同舟云学术

Synthesis of a carborane-substituted bis(phosphanido) cobaltate(i), ligand substitution, and unusual P4 fragmentation

Published:2021 Issue:33 Volume:12 Page:11225-11235
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Coburger Peter¹²^ORCID,Leitl Julia¹,Scott Daniel J.¹^ORCID,Hierlmeier Gabriele¹^ORCID,Shenderovich Ilya G.³^ORCID,Hey-Hawkins Evamarie²^ORCID,Wolf Robert¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Universität Regensburg, 93040 Regensburg, Germany

2. Institute of Inorganic Chemistry, Universität Leipzig, Johannisallee 29, 04103 Leipzig, Germany

3. Institute of Organic Chemistry, Universität Regensburg, 93040 Regensburg, Germany

Abstract

Cobalt and nickel complexes of a new carborane-substituted bis(phosphanido) ligand have been prepared. Reaction of the cobalt complex with white phosphorus (P4) results in a remarkable fragmentation of P4 into P3 and P1 units.

Funder

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02948G

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