Configuration-controllable synthesis of Z/E isomers based on o-carborane-functionalized tetraphenylethene

Author:

Zhou Qin12345,Zhu Miao12345,Chen Wei12345,Qin Na12345,Liu Yujie12345,Zhang Weihua12345,Li Xiang12345ORCID,Sha Ye67895ORCID,Yan Hong101112135ORCID

Affiliation:

1. Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry

2. College of Sciences

3. Nanjing Agricultural University

4. Nanjing 210095

5. China

6. Department of Chemistry and Material Science

7. College of Science

8. Nanjing Forestry University

9. Nanjing 210037

10. State Key Laboratory of Coordination Chemistry

11. School of Chemistry and Chemical Engineering

12. Nanjing University

13. Nanjing

Abstract

Two Z/E isomers, namely, Z-TPE-2Car and E-TPE-2Car, with clear configuration were synthesized using an effective route and have high solid-state fluorescence quantum yields, reaching 99% and 90%, respectively.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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