Facile synthesis, aggregation-induced emission, mechano- and thermochromism of o-carborane–tetraphenylethene dyads with a short CH(OH) linker

Author:

Li Tianrui12,Zhang Hao2,Miao Jinling2,Xu Chunyue1,Nie Yong1ORCID,Liu Guangning2ORCID,Sun Guoxin2ORCID,Jiang Xuchuan13ORCID

Affiliation:

1. Institute for Smart Materials & Engineering, University of Jinan, No. 336 Nanxinzhuang West Road, 250022, Jinan, P. R. China

2. School of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, University of Jinan, No. 336 Nanxinzhuang West Road, 250022, Jinan, P. R. China

3. School of Materials Science and Engineering, University of Jinan, Jinan 250022, P. R. China

Abstract

Four carborane–(F)TPE compounds with a short CH(OH) linker have been synthesized, which could keep the blue emission color with relatively higher emission efficiency compared with that of the parent TPE in the solid state, and exhibit luminescent mechanochromic and thermochromic properties.

Funder

Natural Science Foundation of Shandong Province

University of Jinan

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference65 articles.

1. R. N.Grimes , Carboranes , Elsevier , London , 3rd edn, 2016

2. N. S.Hosmane , Boron science: New technologies and applications , CRC Press , Boca Raton, FL , 2012

3. N. S.Hosmane and R.Eagling , Handbook of Boron Science: With Applications in Organometallics, Catalysis, Materials and Medicine , World Scientific , Singapore , 2018

4. J. A. M. N. S.Hosmane , Y.Zhu and M.Takagaki , Boron and Gadolinium Neutron Capture Therapy for Cancer Treatment , World Scientific , Singapore , 2011

5. E.Hey-Hawkins and C. V.Teixidor , Boron-Based Compounds: Potential and Emerging Applications in Medicine , Wiley , New York , 2018

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