The self-disproportionation of enantiomers (SDE): a menace or an opportunity?-Reference-Cited by-同舟云学术

The self-disproportionation of enantiomers (SDE): a menace or an opportunity?

Published:2018 Issue:7 Volume:9 Page:1718-1739
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Han Jianlin¹²³⁴⁵^ORCID,Kitagawa Osamu⁶⁷⁸⁹^ORCID,Wzorek Alicja¹⁰¹¹¹²¹³¹⁴^ORCID,Klika Karel D.¹⁵¹⁶¹⁷¹⁸^ORCID,Soloshonok Vadim A.¹⁴¹⁹²⁰²¹²²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. State Key Laboratory of Coordination Chemistry

3. Jiangsu Key Laboratory of Advanced Organic Materials

4. Nanjing University

5. 210093 Nanjing

6. Department of Applied Chemistry

7. Shibaura Institute of Technology

8. Tokyo 135-8548

9. Japan

10. Institute of Chemistry

11. Jan Kochanowski University in Kielce

12. 25-406 Kielce

13. Poland

14. Department of Organic Chemistry I

15. Molecular Structure Analysis

16. German Cancer Research Center (DKFZ)

17. D-69009 Heidelberg

18. Germany

19. Faculty of Chemistry

20. University of the Basque Country UPV/EHU

21. 20018 San Sebastián

22. Spain

Abstract

Herein we report on the well-documented, yet not widely known, phenomenon of the self-disproportionation of enantiomers (SDE): the spontaneous fractionation of scalemic material into enantioenriched and -depleted fractions when any physicochemical process is applied.

Funder

National Natural Science Foundation of China

Japan Society for the Promotion of Science

Ministry of Science and Higher Education

Ikerbasque, Basque Foundation for Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC05138G

Reference171 articles.

2. Terminology Related to the Phenomenon ‘Self-Disproportionation of Enantiomers’ (SDE)

3. Purification of Enantiomeric Mixtures in Enantioselective Synthesis: Overlooked Errors and Scientific Basis of Separation in Achiral Environment

4. A. E. Sorochinsky and V. A.Soloshonok , Self-disproportionation of Enantiomers of Enantiomerically Enriched Compounds , in Topics of Current Chemistry, Differentiation of Enantiomers II , ed. V. Schurig , Springer-Verlag GmbH , Berlin, Germany , 2013 , vol. 341 , pp. 301–340

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