Counterintuitive solvation effect of ionic-liquid/DMSO solvents on acidic C–H dissociation and insight into respective solvation
Author:
Affiliation:
1. Center of Basic Molecular Science (CBMS)
2. Department of Chemistry
3. Tsinghua University
4. Beijing
5. China
Abstract
The dependence of PhCH(CN)2pKaon the molar fraction of ionic liquids in ionic–molecular binary mixtures showed a nonlinear three-fragment plot, which was rationalized for the first time by the respective roles of each solvent component for solvation.
Funder
National Natural Science Foundation of China
Tsinghua University
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC06341B
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