Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. Texas State University
3. San Marcos
4. USA
Abstract
We have synthesized the first diamidocarbene (DAC)-supported borenium salt which was found to readily undergo two sequential 1-electron reductions to give a boryl-substituted DAC-centred radical and a DAC-supported aminoborylene.
Funder
Division of Chemistry
Division of Undergraduate Education
Welch Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00300A
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