Affiliation:
1. Organisch-Chemisches Institut Universität Münster 48149 Münster Germany
2. Current address: School of Chemistry and Chemical Engineering Zhang Jiang Institute for Advanced Study Shanghai Jiao Tong University 200240 Shanghai China
Abstract
AbstractThe neutral N‐heterocyclic carbene stabilized bora‐alkene1, conveniently prepared by a BH borenium/hydroboration route, forms stable copper, gold or palladium π‐complexes. The polar bora‐alkene B=C system undergoes regioselective hydroboration reactions with the (C6F5)2BH or C6F5BH2 ⋅ SMe2boranes. The latter reaction involves a subsequent rearrangement that leads to internal hydride vs. isothiocyanate substituent exchange at the borane pair.
Funder
Deutsche Forschungsgemeinschaft
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献