Enantioselective copper-catalysed defluorosilylation of trifluoro-methylated alkenes with silylboronates-Reference-Cited by-同舟云学术

Enantioselective copper-catalysed defluorosilylation of trifluoro-methylated alkenes with silylboronates

Published:2020 Issue:18 Volume:7 Page:2618-2627
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Gao Pan¹²³⁴⁵,Gao Liuzhou⁶⁷³⁴⁸,Xi Longlong¹²³⁴⁵,Zhang Zedong¹²³⁴⁵,Li Shuhua⁶⁷³⁴⁸^ORCID,Shi Zhuangzhi¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. Chemistry and Biomedicine Innovation Center (ChemBIC)

3. School of Chemistry and Chemical Engineering

4. Nanjing University

5. Nanjing

6. Key Laboratory of Mesoscopic Chemistry of Ministry of Education

7. Institute of Theoretical and Computational Chemistry

8. Nanjing 210093

Abstract

An efficient method for the construction of gem-difluoroallylsilanes with high enantiomeric excess via a copper-catalysed defluorosilylation of trifluoromethylated alkenes with silylboronates is described.

Funder

Government of Jiangsu Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00773K

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