Metal–organic frameworks incorporating azobenzene-based ligands as a heterogeneous Lewis-acid catalyst for cyanosilylation of imines-Reference-Cited by-同舟云学术

Metal–organic frameworks incorporating azobenzene-based ligands as a heterogeneous Lewis-acid catalyst for cyanosilylation of imines

Published:2022 Issue:54 Volume:12 Page:35461-35468
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Saeed Aasim¹,Zhang Xiao-Yu¹,Huang Zi-Qing¹,Zhao Xin-Yang¹,Xu Lei²,Zhao Yue¹^ORCID,Sun Wei-Yin¹^ORCID,Zhao Jing¹^ORCID

Affiliation:

1. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

2. Jiangsu Key Lab of Data Engineering and Knowledge Service, School of Information Management, Nanjing University, Nanjing 210023, China

Abstract

Two novel MOFs were synthesized by the reaction of azobenzene-based ligands with Zn(NO3)2/CdCO3 and could both function as heterogeneous Lewis-acid catalysts towards cyanosilylation of imines.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA06858C

Reference74 articles.

1. Robust heterometallic MOF catalysts for the cyanosilylation of aldehydes

2. Low-valent magnesium(i)-catalyzed cyanosilylation of ketones

3. Nanoceria as a recyclable catalyst/support for the cyanosilylation of ketones and alcohol oxidation in cascade

4. Chemically Catalyzed Asymmetric Cyanohydrin Syntheses

5. Highly Enantioselective Cyanosilylation of Aldehydes Catalyzed by a Chiral Oxazaborolidinium Ion

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