Combined description of pressure–volume–temperature and dielectric relaxation of several polymeric and low-molecular-weight organic glass-formers using SL-TS2 approach

Author:

Ginzburg Valeriy V.1ORCID,Zaccone Alessio2ORCID,Casalini Riccardo3ORCID

Affiliation:

1. Department of Chemical Engineering and Materials Science, Michigan State University, East Lansing, MI 48824, USA

2. Department of Physics, University of Milan, via Celoria 16, 20133 Milano, Italy

3. Chemistry Division, Naval Research Laboratory, 4555 Overlook Avenue SW, Washington, DC 20375, USA

Abstract

We apply our “SL-TS2” (two-state Sanchez–Lacombe) model to simultaneously describe dielectric α-relaxation time, τα, and pressure–volume–temperature (PVT) data for multiple polymer and organic glass-formers.

Funder

Office of Naval Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference103 articles.

1. J.Bicerano , Prediction of polymer properties , CRC Press , Boca Raton, FL , 3rd edn, 2002

2. C. B.Roth , Polymer glasses , CRC Press , 2016

3. 50th Anniversary Perspective: Challenges in the Dynamics and Kinetics of Glass-Forming Polymers

4. The glass transition

5. C. A.Angell , Encyclopedia of materials: Science and technology , 2001 , vol. 4, p. 3365

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