Deuteration of heptamethine cyanine dyes enhances their emission efficacy

Author:

Janeková Hana1ORCID,Friedman Hannah C.2,Russo Marina1,Zyberaj Mergime1,Ahmed Tasnim2,Hua Ash Sueh2,Sica Anthony V.2,Caram Justin R.2ORCID,Štacko Peter1ORCID

Affiliation:

1. Department of Chemistry, University of Zurich, Wintherthurerstrasse 190, Zurich 8057, Switzerland

2. Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Drive, Los Angeles, CA 90095-1569, USA

Abstract

We demonstrate that deuteration is a generally applicable strategy that leads to enhanced quantum yields of fluorescence, longer-lived singlet excited states and suppressed rates of non-radiative deactivation processes.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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