Bioinspired motifs in proton and CO2 reduction with 3d-metal polypyridine complexes

Author:

Droghetti Federico1,Amati Agnese1,Ruggi Albert2ORCID,Natali Mirco1ORCID

Affiliation:

1. Department of Chemical, Pharmaceutical and Agricultural Sciences (DOCPAS), University of Ferrara, Via L. Borsari 46, 44121 Ferrara, Italy

2. Department of Chemistry, University of Fribourg, Chemin de Musée 9, CH-1700 Fribourg, Switzerland

Abstract

Mechanistic analysis of catalysis of the hydrogen evolution reaction (HER) and CO2 reduction reaction (CO2RR) by polypyridine complexes of first-row transition metals highlights many similarities with the active sites of Natural enzymes.

Funder

Ministero dell'Università e della Ricerca

Università degli Studi di Ferrara

Université de Fribourg

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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