Tracking the origin of photostability in purine nucleobases: the photophysics of 2-oxopurine

Author:

Martínez-Fernández Lara1234ORCID,Arslancan Serra1234,Ivashchenko Dmytro12345,Crespo-Hernández Carlos E.6789ORCID,Corral Inés123410ORCID

Affiliation:

1. Departamento de Química

2. Universidad Autónoma de Madrid

3. 28049 Madrid

4. Spain

5. Departamento de Química e Bioquímica

6. Department of Chemistry and Center for Chemical Dynamics

7. Case Western Reserve University

8. Cleveland

9. USA

10. IADCHEM

Abstract

Molding purine PES through functionalization: whilst purine C2-substitution maintains the features of the spectroscopic PES of the heterocycle, C6-functionalization reshapes its topography leading to photostable systems.

Funder

Ministerio de Economía y Competitividad

H2020 European Research Council

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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