Isolation and characterization of a tetranuclear Pt–Fe⋯Fe–Pt intermediate en route to the trinuclear Pt–Fe

Isolation and characterization of a tetranuclear Pt–Fe⋯Fe–Pt intermediate en route to the trinuclear Pt–Fe–Pt cluster

Published:2017 Issue:40 Volume:46 Page:14012-14020
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Uemura Kazuhiro¹²³⁴⁵^ORCID,Taoka Masahiro¹²³⁴⁵

Affiliation:

1. Department of Chemistry and Biomolecular Science

2. Faculty of Engineering

3. Gifu University

4. Gifu

5. Japan

Abstract

An intermediate compound of a tetranuclear Pt–Fe⋯Fe–Pt complex in the synthetic process to form a trinuclear Pt–Fe–Pt complex by mixing the “amidate-hanging” Pt mononuclear complex and iron sources was successfully isolated and characterized by single-crystal X-ray analysis and several physical measurements.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02583A

Reference61 articles.

1. Metal–Metal Bonds in Catalysis

2. Rational Syntheses of Multinuclear High-Spin Complexes

3. A pentanuclear iron catalyst designed for water oxidation

4. Introducing a Metal−Metal Multiply Bonded Group as an “Axial Ligand” to Iron: Synthetic Design of a Linear Cr−Cr···Fe Framework

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