Paramagnetic one-dimensional chains containing high-spin manganese atoms showing antiferromagnetic interaction through –Pt–Rh–Rh–Pt

Paramagnetic one-dimensional chains containing high-spin manganese atoms showing antiferromagnetic interaction through –Pt–Rh–Rh–Pt– bonds

Published:2022 Issue:3 Volume:51 Page:946-957
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Uemura Kazuhiro¹^ORCID,Aoki Yusuke¹,Takamori Atsushi¹^ORCID

Affiliation:

1. Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido 1-1, Gifu, 501-1193, Japan

Abstract

Five unpaired electrons localized on high-spin Mn(+2) ions were successfully introduced into a heterometallic one-dimensional chain showing weak antiferromagnetic interaction.

Funder

Ministry of Education, Culture, Sports, Science and Technology

OGAWA Science and Technology Foundation

Asahi Glass Foundation

Tokyo Ohka Foundation for The Promotion of Science and Technology

Shorai Foundation for Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03537A

Reference92 articles.

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5. Electron Delocalization of Mixed‐Valence Diiron Sites Mediated by Group 10 Metal Ions in Heterotrimetallic Fe‐M‐Fe (M=Ni, Pd, and Pt) Chain Complexes

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