Mechanisms of carbon monoxide hydrogenation yielding formaldehyde catalyzed by the representative strong mineral acid, H2SO4, and Lewis–Brønsted superacid, HF/AlF3-Reference-Cited by-同舟云学术

Mechanisms of carbon monoxide hydrogenation yielding formaldehyde catalyzed by the representative strong mineral acid, H2SO4, and Lewis–Brønsted superacid, HF/AlF3

Published:2017 Issue:27 Volume:19 Page:18047-18054
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Rybacka Olimpia¹²³⁴⁵,Czapla Marcin¹²³⁴⁵^ORCID,Skurski Piotr¹²³⁴⁵

Affiliation:

1. Laboratory of Quantum Chemistry

2. Faculty of Chemistry

3. University of Gdańsk

4. 80-308 Gdańsk

5. Poland

Abstract

The HAlF₄ superacid was predicted to effectively reduce the activation barriers of the carbon monoxide hydrogenation mechanism.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP03362A

Reference44 articles.

1. P. A. Chaloner , M. A.Esteruelas, J.Ferenc and L. A.Oro, Homogeneous Hydrogenation, Kluwer Academic Publishers, Dordrecht, 1994

2. G. C. Bond , Catalysis by Metals, Academic Press, London, 1962

3. On the Mechanism for the Hydrogenation of Olefins on Transition-Metal Surfaces: The Chemistry of Ethylene on Pt(111)

4. V. Ponec , in Handbook of Heterogeneous Catalysis, ed. G. Ertl, H. Knözinger and J. Weitkamp, Wiley-VCH, Weinheim, 1997, vol. 4, p. 1876

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