Formic acid disproportionation into formaldehyde triggered by vanadium complexes with iridium catalysis under mild conditions in N-methylation-Reference-Cited by-同舟云学术

Formic acid disproportionation into formaldehyde triggered by vanadium complexes with iridium catalysis under mild conditions in N-methylation

Published:2021 Issue:8 Volume:23 Page:2918-2924
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhou Chao-Zheng¹²³⁴,Zhao Yu-Rou¹²³⁴,Guo Yan-Jun¹²³⁴,Zhang Ping¹²³⁴⁵,Li Yang¹²³⁴^ORCID

Affiliation:

1. Center for Organic Chemistry

2. Frontier Institute of Science and Technology and State Key Laboratory of Multiphase Flow in Power Engineering. Xi'an Jiaotong University

3. Xi'an

4. P. R. China

5. College of Chemistry and Chemical Engineering

Abstract

Renewable HCO₂H disproportionation into CH₂O triggered by vanadium complexes with iridium catalysis under mild conditions in N-methylation is discovered. The gram-scale application of in situ generated CH₂O by HCO₂H disproportionation is demonstrated.

Funder

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC00275A

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