Benzylic C(sp3)–C(sp2) cross-coupling of indoles enabled by oxidative radical generation and nickel catalysis-Reference-Cited by-同舟云学术

Benzylic C(sp3)–C(sp2) cross-coupling of indoles enabled by oxidative radical generation and nickel catalysis

Published:2021 Issue:11 Volume:12 Page:4119-4125
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kim Weonjeong¹²³⁴⁵,Koo Jangwoo¹²³⁴⁵,Lee Hong Geun¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. College of Natural Science

3. Seoul National University

4. Seoul 08826

5. South Korea

Abstract

A mechanistically distinct Ni-catalysed benzylic functionalization of indoles is developed by the facile oxidation of arenes. The method exhibits a wide substrate scope and pronounced chemoselectivity that cannot be accessed via known protocols.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06666D

Reference77 articles.

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