Lewis pairing and frustration of group 13/15 elements geometrically enforced by (ace)naphthalene, biphenylene and (thio)xanthene backbones
Author:
Affiliation:
1. CNRS/Université Paul Sabatier
2. Laboratoire Hetérochimie Fondamentale et Appliquée (LHFA, UMR 5069)
3. 31062 Cedex 09 Toulouse
4. France
Abstract
The synthesis, structure, and reactivity of mixed group 13/group 15 compounds (E13 = B, Al, Ga, In, Tl; E15 = N, P, Sb, Bi) featuring a rigid (ace)naphthalene, biphenylene or (thio)xanthene backbone are discussed in this review.
Funder
Agence Nationale de la Recherche
Centre National de la Recherche Scientifique
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CS/D0CS01259A
Reference91 articles.
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3. A refinement of the structure of biphenylene
4. The Cambridge Structural Database
5. Thioxanthene
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