Cu(i) catalysis for selective condensation/bicycloaromatization of two different arylalkynes: direct and general construction of functionalized C–N axial biaryl compounds-Reference-Cited by-同舟云学术

Cu(i) catalysis for selective condensation/bicycloaromatization of two different arylalkynes: direct and general construction of functionalized C–N axial biaryl compounds

Published:2022 Issue:1 Volume:13 Page:263-273
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shang Qian¹,Tang Haifang¹,Liu Yongping²,Yin MingMing²,Su Lebin¹,Xie Shimin¹,Liu Lixin¹,Yang Wen¹^ORCID,Chen Yi²,Dong Jianyu³^ORCID,Zhou Yongbo¹^ORCID,Yin Shuang-Feng¹^ORCID

Affiliation:

1. Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

2. School of Medicine, Hunan University of Chinese Medicine, Changsha, 410208, China

3. Department of Educational Science, Hunan First Normal University, Changsha 410205, China

Abstract

Selective condensation/bicycloaromatization of two different arylalkynes is firstly developed under ligand-free copper(i)-catalysis, which allows the direct synthesis of C–N axial biaryl compounds in high yields with excellent selectivity and functional group tolerance.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Natural Science Foundation of Hunan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC03865F

Reference107 articles.

1. I.Cepanec , Synthesis of Biaryls , Elsevier , Amsterdam, Netherlands , 2004