Characterizing the n→π* interaction of pyridine with small ketones: a rotational study of pyridine⋯acetone and pyridine⋯2-butanone-Reference-Cited by-同舟云学术

Characterizing the n→π* interaction of pyridine with small ketones: a rotational study of pyridine⋯acetone and pyridine⋯2-butanone

Published:2022 Issue:25 Volume:24 Page:15484-15493
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

López Juan Carlos¹^ORCID,Alkorta Ibon²^ORCID,Macario Alberto¹^ORCID,Blanco Susana¹^ORCID

Affiliation:

1. Departamento de Química Física y Química Inorgánica, Facultad de Ciencias, IU CINQUIMA, Universidad de Valladolid, 47011 Valladolid, Spain

2. Instituto de Química Médica (CSIC), Juan de la Cierva 3, 28006 Madrid, Spain

Abstract

The main interactions between pyridine and small ketones are a N⋯CO n→π* tetrel bond and a C–H⋯O weak hydrogen bond as shown in this rotational study of the complexes pyridine⋯acetone and pyridine⋯2-butanone.

Funder

Consejería de Educación, Junta de Castilla y León

Ministerio de Ciencia e Innovación

Comunidad de Madrid

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01611G

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