Maximized axial helicity in a Pd<sub>2</sub>L<sub>4</sub>cage: inverse guest size-dependent compression and mesocate isomerism-Reference-Cited by-同舟云学术

Maximized axial helicity in a Pd₂L₄cage: inverse guest size-dependent compression and mesocate isomerism

Published:2023 Issue:6 Volume:14 Page:1524-1531
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bloch Witold M.¹²^ORCID,Horiuchi Shinnosuke¹³^ORCID,Holstein Julian J.¹^ORCID,Drechsler Christoph¹,Wuttke Axel⁴,Hiller Wolf¹^ORCID,Mata Ricardo A.⁴^ORCID,Clever Guido H.¹^ORCID

Affiliation:

1. Department of Chemistry and Chemical Biology, TU Dortmund University, Otto-Hahn-Straße 6, 44227 Dortmund, Germany

2. Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, Adelaide, South Australia 5042, Australia

3. Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University, Bunkyo-machi, Nagasaki, 852-8521, Japan

4. Institute of Physical Chemistry, Georg-August University Göttingen, Tammannstraße 6, 37077 Göttingen, Germany

Abstract

The extreme axial twist of a Pd2L4cage facilitates tight encapsulation of mono-anions through prolate-oblate cavity adaptation. In the absence of a suitable guest, the helical cage exists in equilibrium with an ‘unwound’ mesocate isomer.

Funder

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06629G

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