Symmetry controlled excited state dynamics
Author:
Affiliation:
1. Department of Chemistry
2. University of Copenhagen
3. 2100 Copenhagen Ø
4. Denmark
5. Brown University
6. Providence
7. USA
Abstract
Symmetry effects in internal conversion are studied by means of two isomeric cyclic tertiary aliphatic amines in a velocity map imaging (VMI) experiment on the femtosecond timescale. We conclude that lessening the symmetry of the molecule leads to loss of coherence after internal conversion between Rydberg states.
Funder
Army Research Office
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP05950K
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