Comparison of a dimeric and a monomeric indium-quinolinato complex: synthesis, structure and photoluminescence
Author:
Affiliation:
1. Department of Chemistry
2. University of the Free State
3. Bloemfontein 9300
4. South Africa
5. Department of Physics
Abstract
Two indium(iii) complexes, mer-[In(Ox)3]·2H2O (1) and [In2(Ox)2Cl2-μ-[κ2-O,O′-(Ox)2]]·C7H8 (2) (Ox = 8-hydroxyquinolinate), were synthesized and characterised for comparison by NMR, X-ray diffraction and photoluminescence.
Funder
National Research Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ03865B
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1. Kinetic‐Mechanistic and Solid‐State Study of the Oxidative Addition and Migratory Insertion of Iodomethane to [Rhodium( S , O ‐ BdiPT or N , O‐ox )(CO)(PR 1 R 2 R 3 )] Complexes
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3. Rhodium-Catalyzed anti-Markovnikov Addition of Secondary Amines to Arylacetylenes at Room Temperature
4. Novel Fluorinated 8-Hydroxyquinoline Based Metal Ionophores for Exploring the Metal Hypothesis of Alzheimer’s Disease
5. Distorted octahedral environments in tricarbonylrhenium(I) complexes of 5-[2-(2,4,6-trimethylphenyl)diazen-1-yl]quinolin-8-olate and 5,7-bis[2-(2-methylphenyl)diazen-1-yl]quinolin-8-olate
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1. Synthesis and Biological Evaluation of a Series of Quinoline‐Based Quinazolinones and Carbamic Anhydride Derivatives;ChemistrySelect;2023-01-18
2. Solution speciation and human serum protein binding of indium(III) complexes of 8-hydroxyquinoline, deferiprone and maltol;JBIC Journal of Biological Inorganic Chemistry;2022-03-03
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