Kinetic‐Mechanistic and Solid‐State Study of the Oxidative Addition and Migratory Insertion of Iodomethane to [Rhodium( S , O ‐ BdiPT or N , O‐ox )(CO)(PR 1 R 2 R 3 )] Complexes
Author:
Affiliation:
1. Department of Chemistry University of the Free State PO Box 339 9300 Bloemfontein South Africa
2. R&D Division Sasol Technology 1 Klasie Havenga Street 1948 Sasolburg South Africa
Funder
Sasol
South African Agency for Science and Technology Advancement
UFS
Publisher
Wiley
Subject
Inorganic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.201800293
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5. Steric vs. electronic anomaly observed from iodomethane oxidative addition to tertiary phosphine modified rhodium(i) acetylacetonato complexes following progressive phenyl replacement by cyclohexyl [PR3 = PPh3, PPh2Cy, PPhCy2 and PCy3]
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