Room temperature formation of organic–inorganic lead halide perovskites: design of nanostructured and highly reactive intermediates

Author:

Zhang Hong123ORCID,Li Dan45678,Cheng Jiaqi123,Lin Francis9101112,Mao Jian123,Jen Alex K.-Y.9101112,Grätzel Michael1314151617,Choy Wallace C. H.123

Affiliation:

1. Department of Electrical and Electronic Engineering

2. The University of Hong Kong

3. China

4. Key Laboratory of Luminescence and Optical Information

5. Ministry of Education

6. School of Science

7. Beijing Jiaotong University

8. Beijing 100044

9. Department of Materials Science & Engineering

10. University of Washington

11. Seattle

12. United States

13. Laboratory for Photonics and Interfaces

14. Institute of Chemical Sciences and Engineering

15. School of Basic Sciences

16. Ecole Polytechnique Fédérale de Lausanne

17. CH-1015 Lausanne

Abstract

We propose a room-temperature scheme of ligand-promoted formation of high-quality perovskite films through the judicious design of nanostructured PbI2·(L)x intermediates, where L denotes the ligand. The mechanisms and features of the ideal ligand have been investigated through a combined experimental and theoretical study.

Funder

Office of Naval Research Global

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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