Ferroelastic phase transition and the role of volume strain in the structural trapping of a metastable quenched low-spin high-symmetry phase in [Ru0.35Fe0.65(ptz)6](BF4)2-Reference-Cited by-同舟云学术

Ferroelastic phase transition and the role of volume strain in the structural trapping of a metastable quenched low-spin high-symmetry phase in [Ru_0.35Fe_0.65(ptz)₆](BF₄)₂

Published:2023 Issue:25 Volume:25 Page:3588-3597
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Valverde-Muñoz Francisco Javier¹^ORCID,Torres Ramírez Ricardo Guillermo¹^ORCID,Ulhe Abhilash¹^ORCID,Trzop Elzbieta¹²^ORCID,Dutta Mousumi³,Das Chinmoy³,Chakraborty Pradip³,Collet Eric¹²⁴^ORCID

Affiliation:

1. Univ Rennes, CNRS, IPR (Institut de Physique de Rennes) – UMR 6251, 35000 Rennes, France

2. Department of Chemistry, DYNACOM IRL2015 University of Tokyo – CNRS – UR1, 7-3-1 Hongo, Tokyo 113-0033, Japan

3. Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur-721302, India

4. Institut universitaire de France (IUF), France

Abstract

Spin-crossover materials exhibit thermal conversion of their electronic state from low to high spin, involving both intra- and inter-molecular structural reorganisations, eventually accompanied by symmetry breaking, within the crystal.

Funder

Generalitat Valenciana

Science and Engineering Research Board

European Social Fund

Agence Nationale de la Recherche

Indian Institute of Technology Kharagpur

Région Bretagne

Université de Rennes 1

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry