The effect of inert dopant ions on spin-crossover materials is not simply controlled by chemical pressure-Reference-Cited by-同舟云学术

The effect of inert dopant ions on spin-crossover materials is not simply controlled by chemical pressure

Published:2023 Issue:37 Volume:11 Page:12570-12582
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Ghosh Prabir¹,Pask Christopher M.²,Vasili Hari Babu³,Yoshinari Nobuto⁴^ORCID,Konno Takumi⁴^ORCID,Cespedes Oscar³,Enachescu Cristian⁵,Chakraborty Pradip⁶^ORCID,Halcrow Malcolm A.²^ORCID

Affiliation:

1. Department of Mechanical Engineering, Indian Institute of Technology Kharagpur, Kharagpur-721302, India

2. School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK

3. School of Physics and Astronomy, W. H. Bragg Building, University of Leeds, Leeds LS2 9JT, UK

4. Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan

5. Faculty of Physics, Alexandru Ioan Cuza University, 700506 Iasi, Romania

6. Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur-721302, India

Abstract

Unexpectedly, the spin-crossover midpoint temperature (T½) in [FezM1−z(bpp)2][BF4]2 is increased by doping with ruthenium(ii). This reflects that different structure:function relationships operate in these materials for different dopant ions ‘M’.

Funder

Diamond Light Source

Royal Society

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TC/D3TC02683C

Reference110 articles.

1. in Spin Crossover in Transition Metal Compounds I–III: Topics in Current Chemistry , ed. P. Gütlich and H. A. Goodwin , Springer-Verlag , Berlin , 2004 , vols. 233–235

2. in Spin-crossover materials – properties and applications , ed. M. A. Halcrow , John Wiley & Sons , Chichester, UK , 2013 , p. 568

3. Preface and introduction

4. Emerging trends in spin crossover (SCO) based functional materials and devices

5. Spin Crossover Nanomaterials: From Fundamental Concepts to Devices

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1. Structural Consequences of Different Metal Compositions in the Doped Spin‐Crossover Crystals [Fe_zM_1−z(bpp)₂][BF₄]₂ (M=Ni, Zn; bpp=2,6‐Bis{Pyrazol‐1‐yl}Pyridine);European Journal of Inorganic Chemistry;2024-08-21

2. Mix and match – controlling the functionality of spin-crossover materials through solid solutions and molecular alloys;Dalton Transactions;2024

3. Activating a high-spin iron(ii) complex to thermal spin-crossover with an inert non-isomorphous molecular dopant;Dalton Transactions;2024