Guanidinium/ammonium competition and proton transfer in the interaction of the amino acid arginine with the tetracarboxylic 18-crown-6 ionophore
Author:
Affiliation:
1. Department of Physical
2. Chemical and Natural Systems
3. Universidad Pablo de Olavide
4. E-41013 Seville
5. Spain
6. Radboud University
7. Institute for Molecules and Materials
8. FELIX Laboratory
9. Toernooiveld 7c
10. The Netherlands
Abstract
The binding of arginine by the 18-crown-6 tetracarboxylic ionophore relies on extensive host–guest redistribution of electronic charge and proton transfer.
Funder
Horizon 2020 Framework Programme
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP07975C
Reference45 articles.
1. Arginine: Its pKavalue revisited
2. Arginine residues at internal positions in a protein are always charged
3. Unambiguous Determination of Protein Arginine Ionization States in Solution by NMR Spectroscopy
4. Abiotic Guanidinium Receptors for Anion Molecular Recognition and Sensing
5. Noncovalent Binding between Guanidinium and Anionic Groups: Focus on Biological- and Synthetic-Based Arginine/Guanidinium Interactions with Phosph[on]ate and Sulf[on]ate Residues
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