Surface differences of oxide nanocrystals determined by geometry and exogenously coordinated water molecules

Author:

Chen Junchao12,Wu Xin-Ping3ORCID,Hope Michael A.4ORCID,Lin Zhiye1,Zhu Lei5,Wen Yujie1,Zhang Yixiao2,Qin Tian2,Wang Jia3ORCID,Liu Tao6ORCID,Xia Xifeng7,Wu Di8,Gong Xue-Qing3ORCID,Tang Weiping5,Ding Weiping1ORCID,Liu Xi2ORCID,Chen Liwei29,Grey Clare P.4ORCID,Peng Luming11011ORCID

Affiliation:

1. Key Laboratory of Mesoscopic Chemistry of MOE, Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, 163 Xianlin Road, Nanjing 210023, China

2. School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, In situ Center for Physical Sciences, Shanghai Jiao Tong University, Shanghai 200240, China

3. Key Laboratory for Advanced Materials, Centre for Computational Chemistry, Research Institute of Industrial Catalysis, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China

4. Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK

5. State Key Laboratory of Space Power Technology, Shanghai Institute of Space Power-Sources (SISP), Shanghai Academy of Spaceflight Technology, Shanghai 200245, China

6. Shanghai Key Laboratory of Chemical Assessment and Sustainability, Department of Chemistry, Tongji University, Shanghai 200092, China

7. Analysis and Testing Center, Nanjing University of Science and Technology, Nanjing 210094, China

8. College of Food Science and Engineering/Collaborative Innovation Center for Modern Grain Circulation and Safety/Key Laboratory of Grains and Oils Quality Control and Processing, Nanjing University of Finance and Economics, Nanjing 210023, China

9. i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences, Suzhou 215123, China

10. Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing 210093, China

11. Frontiers Science Center for Critical Earth Material Cycling (FSC-CEMaC), Nanjing University, Nanjing, Jiangsu, 210023, China

Abstract

Both atomic geometry and the influence of surroundings (e.g., exogenously coordinated water) are key issues for determining the chemical environment of oxide surfaces, whereas the latter is usually ignored and should be considered in future studies.

Funder

Newton Fund

National Natural Science Foundation of China

National Key Research and Development Program of China

Royal Society

Fundamental Research Funds for the Central Universities

Nanjing University

Priority Academic Program Development of Jiangsu Higher Education Institutions

European Research Council

Project 211

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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