Double-resonance<sup>17</sup>O NMR experiments reveal unique configurational information for surface organometallic complexes-Reference-Cited by-同舟云学术

Double-resonance¹⁷O NMR experiments reveal unique configurational information for surface organometallic complexes

Published:2023 Issue:31 Volume:59 Page:4604-4607
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Perras Frédéric A.¹²^ORCID,Arroyave Alejandra³,Southern Scott A.¹^ORCID,Lamb Jessica V.³^ORCID,Li Yuting¹^ORCID,LaPointe Anne⁴^ORCID,Delferro Massimiliano³⁵^ORCID

Affiliation:

1. Chemical and Biological Sciences Division, Ames National laboratory, Ames, IA 50011, USA

2. Department of Chemistry, Iowa State University, Ames, IA, 50011, USA

3. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, USA

4. Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA

5. Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, USA

Abstract

17O-Labeling supports enables the determination of the 3D configuration of surface organometallic complexes. The procedure also allows for probing of the metal's chemical environment through 2D experiments involving the metal-bound oxygen.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00899A

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5. DNP-Enhanced Ultrawideline Solid-State NMR Spectroscopy: Studies of Platinum in Metal–Organic Frameworks

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