Large polarization of push–pull “Cruciforms” via coordination with lanthanide ions

Author:

Benedini Sara1,Zheng Yeting2,Nitti Andrea1ORCID,Mazza Mercedes M. A.2ORCID,Dondi Daniele1,Raymo Françisco M.2,Pasini Dario1ORCID

Affiliation:

1. Department of Chemistry and INSTM Research Unit, University of Pavia, Via Taramelli 10 – 27100 Pavia, Italy

2. Laboratory for Molecular Photonics, Department of Chemistry, University of Miami, 1301 Memorial Drive, Coral Gables, Florida 33146-0431, USA

Abstract

“Bent” or “cruciform” shaped conjugated push–pull compounds exhibit striking differences in their supramolecular recognition of lanthanide cations, with in an outstanding supramolecular polarization.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Università degli Studi di Pavia

Regione Lombardia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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