A strong steric hindrance effect on ground state, excited state, and charge separated state properties of a CuI-diimine complex captured by X-ray transient absorption spectroscopy-Reference-Cited by-同舟云学术

A strong steric hindrance effect on ground state, excited state, and charge separated state properties of a CuI-diimine complex captured by X-ray transient absorption spectroscopy

Published:2014 Issue:47 Volume:43 Page:17615-17623
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Huang J.¹²³,Mara M. W.¹²³⁴⁵,Stickrath A. B.¹²³,Kokhan O.¹²³,Harpham M. R.¹²³,Haldrup K.⁶⁷⁸⁹¹⁰,Shelby M. L.⁴⁵¹¹,Zhang X.¹²²³,Ruppert R.¹³¹⁴¹⁵,Sauvage J.-P.¹⁶¹⁴¹⁵,Chen L. X.¹²³⁴⁵

Affiliation:

1. Chemical Sciences and Engineering Division

2. Argonne National Laboratory

3. Lemont, USA

4. Department of Chemistry

5. Northwestern University

6. Molecular Movies Group

7. NEXMAP section

8. Department of Physics

9. Technical University of Denmark

10. 2800 Kgs. Lyngby, Denmark

11. Evanston, USA

12. X-ray Science Division

13. Institut de Chimie

14. Université de Strasbourg

15. 67000 Strasbourg, France

16. Institut de Science et d'Ingénierie Supramoléculaires

Abstract

Steady-state and transient structures of a copper diimine dye sensitizer on TiO₂ nanoparticles undergoing photoinduced interfacial electron transfer are determined.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02046D

Reference41 articles.

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5. Synthesis of a new copper(i) complex, [Cu(tmdcbpy)2]+ (tmdcbpy = 4,4′,6,6′-tetramethyl-2,2′-bipyridine-5,5′-dicarboxylic acid), and its application to solar cells

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