Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

Author:

Kim Yeong Hun1234,Tran T. Thao1567,Halasyamani P. Shiv1567,Ok Kang Min1234

Affiliation:

1. Department of Chemistry

2. Chung-Ang University

3. Seoul 156-756

4. Republic of Korea

5. University of Houston

6. Houston

7. USA

Abstract

The IO3 groups in Na2Sn(IO3)6 are aligned in a parallel manner attributed to the six-coordinate Na+ cation, whereas the IO3 polyhedra in Cs2Sn(IO3)6 rotate with respect to Sn4+ due to the nine-coordinate Cs+ cation.

Funder

National Research Foundation of Korea

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference52 articles.

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3. M. E. Lines and A. M.Glass, Principles and Applications of Ferroelectrics and Related Materials, Oxford University Press, Oxford, UK, 1991

4. S. B. Lang and D. K.Das-Gupta, Handbook of Advanced Electronic and Photonic Materials and Devices, Academic Press, San Francisco, USA, 2001

5. T. Hahn , International Tables for Crystallography, Volume A: Space Group Symmetry, Kluwer Academic, Dordrecht, The Netherlands, 2006

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