Difluoromethylenation of fullerene C70 provides isomeric diversity and availability of equatorial [5,6]-homofullerene C70(CF2)-Reference-Cited by-同舟云学术

Difluoromethylenation of fullerene C₇₀ provides isomeric diversity and availability of equatorial [5,6]-homofullerene C₇₀(CF₂)

Published:2022 Issue:27 Volume:24 Page:16816-16826
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Brotsman Victor A.¹^ORCID,Lukonina Natalia S.¹,Malkin Nikita A.¹,Rybalchenko Alexey V.¹,Belov Nikita M.¹,Goryunkov Alexey A.¹^ORCID

Affiliation:

1. Chemistry Department, Lomonosov Moscow State University, Leninskie Gory, 1-3, 119991, Moscow, Russia

Abstract

We report synthesis, isolation, spectroscopic characterization, and electrochemical study of the novel [5,6]-open C70(CF2) isomer III along with the already known [6,6]-closed and [6,6]-open C70(CF2) isomers I and II.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01922A

Reference57 articles.

1. Review: Fullerene based acceptors for efficient bulk heterojunction organic solar cell applications

2. Emerging electronic applications of fullerene derivatives: an era beyond OPV

3. Non-fullerene acceptors for organic solar cells

4. A History and Perspective of Non‐Fullerene Electron Acceptors for Organic Solar Cells

5. Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells

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