Exploring structure, temperature and activity correlations in the selective oxidation of lower olefins over Bi–Mo–Co–Fe–O catalysts by spatial reactor profile measurements

Author:

Klag Linda1ORCID,Weber Sebastian12ORCID,Horn Raimund3,Sheppard Thomas L.12ORCID,Grunwaldt Jan-Dierk12ORCID

Affiliation:

1. Institute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany

2. Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, Germany

3. Institute of Chemical Reaction Engineering, Hamburg University of Technology, 21073 Hamburg, Germany

Abstract

Improving process efficiency in selective oxidation of lower olefins over mixed metal oxide catalysts requires profound knowledge of the dynamic behaviour of exothermic reactions along the reactor.

Funder

Deutsche Forschungsgemeinschaft

Agence Nationale de la Recherche

Karlsruhe Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Reference67 articles.

1. J.Haber , Fundamentals of Hydrocarbon Oxidation, in Handbook of Heterogeneous Catalysis , ed. G. Ertl , H. Knözinger , F. Schüth and J. Weitkamp , Wiley-VCH , Weinheim , 2008 , pp. 3359–3384

2. R. K.Grasselli and J. D.Burrington , Oxidation of Low-Molecular-Weight Hydrocarbons, in Handbook of Heterogeneous Catalysis , ed. G. Ertl , H. Knözinger , F. Schüth and J. Weitkamp , Wiley-VCH , Weinheim , 2008 , pp. 3479–3489

3. G.Centi , F.Cavani and F.Trifirò , Trends and Outlook in Selective Oxidation, Selective Oxidation by Heterogeneous Catalysis , Springer , Boston, MA , 2001 , pp. 1–24

4. D.Arntz , A.Fischer , M.Höpp , S.Jacobi , J.Sauer , T.Ohara , T.Sato , N.Shimizu and H.Schwind , Acrolein and Methacrolein, Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH , Weinheim , 2007 , vol. 1 , pp. 329–346

5. U.Bornscheuer , R. W.Fischer , L. J.Gooßen , R.Schlögl , R.Schomäcker and S.Schunk , Katalytische Oxidationsreaktionen als Schlüsseltechnologie, Katalytische Oxidationsreaktionen als Schlüsseltechnologie , German Catalysis Society , 2015 , ISBN: 978-3-89746-176-5, https://dechema.de/dechema_media/Downloads/Positionspapiere/Positionspapier_GeCatS_2015_final.pdf , (accessed 15.01.2024)

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