Photochemical cyclopropanation in aqueous micellar media – experimental and theoretical studies

Author:

Milton Joseph P.1ORCID,Milanowski Adam12ORCID,Andersson Martin3ORCID,Gryko Dorota1

Affiliation:

1. Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, Warsaw 01-224, Poland

2. Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, Warsaw 00-664, Poland

3. Center for Integrative Petroleum Research, King Fahd University of Petroleum and Minerals, Dhahran 31261, Kingdom of Saudi Arabia

Abstract

Photochemical cyclopropanation of styrenes with diazo compounds or their precursors can be performed in micellar systems. COSMO-RS studies revealed that the reactivity correlates with the predicted critical micelle concentration, with higher CMC values delivering higher yields.

Funder

Narodowe Centrum Nauki

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

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