Value-added chemicals from biomass-derived furans: radical functionalisations of 5-chloromethylfurfural (CMF) by metal-free ATRA reactions-Reference-Cited by-同舟云学术

Value-added chemicals from biomass-derived furans: radical functionalisations of 5-chloromethylfurfural (CMF) by metal-free ATRA reactions

Published:2021 Issue:7 Volume:19 Page:1626-1631
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Dasi Rajesh¹²³⁴^ORCID,Schmidhuber Daniel⁵⁶⁷⁴,Gronbach Lisa Marie¹²³⁴,Rehbein Julia⁵⁶⁷⁴^ORCID,Brasholz Malte¹²³⁴^ORCID

Affiliation:

1. University of Rostock

2. Institute of Chemistry

3. 18055 Rostock

4. Germany

5. University of Regensburg

6. Institute of Organic Chemistry

7. 93053 Regensburg

Abstract

Biomass-derived 5-chloromethylfurfural (CMF) can efficiently be functionalised by way of metal-free, Et₃B/O₂-induced atom transfer radical addition (ATRA) reactions with styrenes.

Funder

Leibniz-Gemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00013F

Reference30 articles.

1. Current Situation of the Challenging Scale‐Up Development of Hydroxymethylfurfural Production

2. Hydroxymethylfurfural, A Versatile Platform Chemical Made from Renewable Resources

3. Towards the Efficient, Total Glycan Utilization of Biomass

4. Highly efficient dehydration of carbohydrates to 5-(chloromethyl)furfural (CMF), 5-(hydroxymethyl)furfural (HMF) and levulinic acid by biphasic continuous flow processing

5. 5-(Chloromethyl)furfural is the New HMF: Functionally Equivalent But More Practical in Terms of its Production From Biomass

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