Nitrogen‐doped Carbon Dots as Biobased Catalysts for Visible Light Driven 1,2‐Functionalization of Olefins through an Atom Transfer Radical Addition Process-Reference-Cited by-同舟云学术

Nitrogen‐doped Carbon Dots as Biobased Catalysts for Visible Light Driven 1,2‐Functionalization of Olefins through an Atom Transfer Radical Addition Process

Published:2023-07-06 Issue:17 Volume:15 Page:
ISSN:1867-3880
Container-title:ChemCatChem
language:en
Short-container-title:ChemCatChem

Author:

Hamadamin Abdullah¹²,Benazzi Valentina¹,Campalani Carlotta³^ORCID,Quattri Luca¹,Ravelli Davide¹^ORCID,Hussain Faiq⁴,Perosa Alvise³^ORCID,Selva Maurizio³^ORCID,Protti Stefano¹^ORCID

Affiliation:

1. Photogreen Lab Department of Chemistry University of Pavia Viale Taramelli 12 27100 Pavia Italy

2. Department of Pharmaceutical Chemistry Pharmacy College Hawler Medical University Erbil Kurdistan Region Iraq

3. Dipartimento di Scienze Molecolari e Nanosistemi Università Ca' Foscari Via Torino 155 30172 Venezia Mestre Italy

4. Medical Analysis Department Faculty of Applied Science Tishk International University Erbil Kurdistan Region Iraq

Abstract

AbstractAmorphous nitrogen‐doped carbon dots (a‐N‐CDs) have been obtained under hydrothermal conditions from citric acid and diethylenetriamine (DETA) as the carbon and nitrogen source, respectively. Such materials exhibit a significant absorption in the visible light region and have been successfully employed as photoredox catalyst under violet LED irradiation for the 1,2‐difunctionalization of olefins via an atom transfer radical addition (ATRA) process. The reported approach occurs smoothly under metal‐free conditions in an aqueous medium, showcasing the (yet not completely explored) applications of such bio‐derived carbon materials in organic synthesis.

Funder

Fondazione Cariplo

Publisher

Wiley

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis

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