Theoretical unraveling of the separation of trivalent Am and Eu ions by phosphine oxide ligands with different central heterocyclic moieties

Author:

Huang Pin-Wen1ORCID

Affiliation:

1. Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, People's Republic of China

Abstract

Am(iii)/Eu(iii) separation mechanism of three phosphine oxide ligands with different central moieties were investigated using DFT method, the affinity of donor O atoms seems to have an opposite influence on the ligands’ separation ability.

Funder

Department of Education of Zhejiang Province

Zhejiang University of Water Resources and Electric Power

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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