Emergence of the structure-directing role of f-orbital overlap-driven covalency
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry
Link
http://www.nature.com/articles/s41467-019-08553-y.pdf
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3. Hayton, T. W. Metal-ligand multiple bonding in uranium: structure and reactivity. Dalton. Trans. 39, 1145–1158 (2010).
4. Seaman, L. A. et al. Probing the 5f orbital contribution to the bonding in a U(V) ketimide complex. J. Am. Chem. Soc. 134, 4931–4940 (2012).
5. Minasian, S. G. et al. Determining relative f and d orbital contributions to M-Cl covalency in MCl6 2− (M = Ti, Zr, Hf, U) and UOCl5 − using Cl K-edge X-ray absorption spectroscopy and time-dependent density functional theory. J. Am. Chem. Soc. 134, 5586–5597 (2012).
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