Charge transfer excitons in a donor–acceptor amphidynamic crystal: the role of dipole orientational order

Author:

Macdonald Joshua W. R.12345,Piana Giacomo67895,Comin Massimiliano101112ORCID,von Hauff Elizabeth13141516ORCID,Kociok-Köhn Gabriele171845ORCID,Bowen Chris191845,Lagoudakis Pavlos67895,D'Avino Gabriele101112ORCID,Da Como Enrico12345ORCID

Affiliation:

1. Centre for Photonics and Photonic Materials (CPPM) and Department of Physics

2. University of Bath

3. Claverton Down

4. Bath BA2 7AY

5. UK

6. Physics and Astronomy

7. University of Southampton

8. University Road

9. Southampton SO17 1BJ

10. Institut Néel CNRS and Université Grenoble Alpes

11. F-38042 Grenoble

12. France

13. Department of Physics and Astronomy

14. Vrije Universiteit, de Boelelaan 1081

15. 1081 HV Amsterdam

16. The Netherlands

17. Material and Chemical Characterization Facility (MC2)

18. University of Bath, Claverton Down

19. Department of Mechanical Engineering

Abstract

Large amplitude motions in molecular solids are responsible for anomalous electrical characteristics in amphidynamic crystals. Here we explore the implications for charge transfer excitons photophysics.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

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