Ketone transformation as a pathway to inherently chiral rigidified calix[4]arenes

Author:

Tlustý Martin12345ORCID,Spálovská Dita6745,Kohout Michal12345ORCID,Eigner Václav8745,Lhoták Pavel12345ORCID

Affiliation:

1. Department of Organic Chemistry

2. University of Chemistry and Technology

3. Prague (UCTP)

4. 166 28 Prague 6

5. Czech Republic

6. Department of Analytical Chemistry

7. UCTP

8. Department of Solid State Chemistry

Abstract

A novel strategy for bridging the upper rim of calix[4]arenes consisting in carbonyl group formation and subsequent “extension” into a two-atom bridge is presented.

Funder

Grantová Agentura České Republiky

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference33 articles.

1. P. Neri , J. L.Sessler and M. X.Wang , Calixarenes and Beyond , Springer , Cham, Switzerland , 2016

2. C. D. Gutsche , Calixarenes: an Introduction , Royal Society of Chemistry , Cambridge, UK , 2nd edn, 2008

3. J. Vicens , J.Harrowfield and L.Backlouti , Calixarenes in the Nanoworld , Springer , Dordrecht, The Netherlands , 2007

4. Z. Asfari , V.Böhmer , J.Harrowfield and J.Vicens , Calixarenes , Kluwer , Dordrecht, The Netherlands , 2001

5. L. Mandolini and R.Ungaro , Calixarenes in Action , Imperial College Press , London , 2000

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