Gold(<scp>i</scp>)-catalysed hydroarylations of alkynes for the synthesis of inherently chiral calix[4]arenes-Reference-Cited by-同舟云学术

Gold(i)-catalysed hydroarylations of alkynes for the synthesis of inherently chiral calix[4]arenes

Published:2023 Issue:19 Volume:21 Page:4072-4083
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Giovanardi Gabriele¹^ORCID,Scarica Gabriele¹^ORCID,Pirovano Valentina²^ORCID,Secchi Andrea¹^ORCID,Cera Gianpiero¹^ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy

2. Dipartimento di Scienze Farmaceutiche, Sezione di Chimica Generale e Organica “A. Marchesini”, Università degli Studi di Milano, Via Venezian, 21, 20133 Milano, Italy

Abstract

We report a step- and atom economical approach for the meta-functionalisation of calix[4]arene macrocycles by intramolecular gold(i)-catalysed hydroarylation of alkynes.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB00603D

Reference40 articles.

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2. C. D.Gutsche , Calixarenes: An Introduction , Royal Society of Chemistry , Cambridge, U.K. , 2nd edn, 2008

3. Macrocycles as Ion Pair Receptors