Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase-Reference-Cited by-同舟云学术

Carbonic acid monoethyl ester as a pure solid and its conformational isomerism in the gas-phase

Published:2017 Issue:36 Volume:7 Page:22222-22233
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bernard Jürgen¹²³⁴⁵,Köck Eva-Maria¹²³⁴⁵^ORCID,Huber Roland G.⁶⁷²³⁴,Liedl Klaus R.⁶⁷²³⁴,Call Ludwig⁸²³⁴,Schlögl Robert⁵⁹¹⁰,Grothe Hinrich¹¹¹²¹³⁴^ORCID,Loerting Thomas¹²³⁴^ORCID

Affiliation:

1. Institute of Physical Chemistry

2. University of Innsbruck

3. A-6020 Innsbruck

4. Austria

5. Max-Planck-Institut für chemische Energiekonversion

6. Institute of General

7. Inorganic and Theoretical Chemistry

8. Institute of Organic Chemistry

9. D-45470 Mülheim an der Ruhr

10. Germany

11. Institute of Materials Chemistry

12. TU Wien

13. A-1060 Vienna

Abstract

The ethyl hemiester of carbonic acid is prepared as a pure solid and sublimed to the gas phase, in spite of claims of its instability. FT-IR spectroscopy combined with ab initio calculations reveals a 5 : 1 ratio of the two most stable conformers.

Funder

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02792C

Reference35 articles.

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