Proton dynamics of two-dimensional oxalate-bridged coordination polymers

Author:

Miyatsu Satoshi123,Kofu Maiko123,Nagoe Atsushi12345,Yamada Takeshi12345,Sadakiyo Masaaki678910,Yamada Teppei6789,Kitagawa Hiroshi451167,Tyagi Madhusudan121314,García Sakai Victoria1516171819,Yamamuro Osamu12345

Affiliation:

1. Institute for Solid State Physics

2. University of Tokyo

3. Kashiwa, Japan

4. Core Research for Evolutional Science and Technology (CREST)

5. Japan Science and Technology Agency (JST)

6. Graduate School of Science

7. Kyoto University

8. Kitashirakawa Oiwake-cho

9. Sakyo-ku, Japan

10. International Institute for Carbon-Neutral Energy Research (WPI-I2CNER)

11. Chiyoda-ku, Japan

12. NIST Center for Neutron Research

13. National Institute of Standards and Technology

14. Gaithersburg, USA

15. ISIS Facility

16. Rutherford Appleton Laboratory

17. Harwell Science & Innovation Campus

18. Chilton

19. Didcot, UK

Abstract

The dynamics of H2O molecules and NH4+ ions in a new type of crystalline proton conductor (NH4)2(adp)[Zn2(ox)3]·3H2O has been investigated by quasielastic neutron scattering techniques to elucidate the proton conduction mechanism.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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