Hysteretic Adsorption and Desorption of Hydrogen by Nanoporous Metal-Organic Frameworks-Reference-Cited by-同舟云学术

Hysteretic Adsorption and Desorption of Hydrogen by Nanoporous Metal-Organic Frameworks

Published:2004-11-05 Issue:5698 Volume:306 Page:1012-1015
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Zhao Xuebo¹²,Xiao Bo¹²,Fletcher Ashleigh J.¹²,Thomas K. Mark¹²,Bradshaw Darren¹²,Rosseinsky Matthew J.¹²

Affiliation:

1. Northern Carbon Research Laboratories, School of Natural Sciences, Bedson Building, University of Newcastle upon Tyne, Newcastle upon Tyne, NE1 7RU, UK.

2. Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD, UK.

Abstract

Adsorption and desorption of hydrogen from nanoporous materials, such as activated carbon, is usually fully reversible. We have prepared nanoporous metal-organic framework materials with flexible linkers in which the pore openings, as characterized in the static structures, appear to be too small to allow H 2 to pass. We observe hysteresis in their adsorption and desorption kinetics above the supercritical temperature of H 2 that reflects the dynamical opening of the “windows” between pores. This behavior would allow H 2 to be adsorbed at high pressures but stored at lower pressures.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference24 articles.

1. “Grand challenge for basic and applied research on hydrogen storage: statement of objectives ” available at www.eere.energy.gov/hydrogenandfuelcells/docs/gc_h2_storage.doc.

2. G. Gundiah, A. Govindaraj, N. Rajalakshmi, K. S. Dhathathreyan, C. N. R. Rao, J. Mater. Sci.85, 209 (2003).

3. Compensation Effect for the Kinetics of Adsorption/Desorption of Gases/Vapors on Microporous Carbon Materials

4. Adsorption Kinetics and Size Exclusion Properties of Probe Molecules for the Selective Porosity in a Carbon Molecular Sieve Used for Air Separation

5. Hydrogen Sorption in Functionalized Metal−Organic Frameworks

Cited by 1213 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Progressive gas adsorption squeezing through the narrow channel of a soft porous crystal of [Co2(4,4′-bipyridine)3(NO3)4];Communications Materials;2024-09-02

2. A synergistic approach: cellulose nanocrystals blended polyimide-based covalent organic framework for advanced supercapacitors and hydrogen evolution;Journal of Materials Science: Materials in Electronics;2024-07

3. Recent advances in mono-lacunary Keggin-type polyoxometalate-based crystalline materials: From synthetic strategies, diverse structures to functional applications;Coordination Chemistry Reviews;2024-06

4. Highly-dispersed surface NiO species and exposed Ni (200) facets facilitating activation of furan ring for high-efficiency total hydrogenation of furfural;Applied Catalysis B: Environmental;2024-04

5. Large hysteretic hydrogen adsorption in Double Wall Carbon Nanotubes bundles;Carbon;2024-02