High-valent osmium iminoxolene complexes
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. 251 Nieuwland Science Hall
3. University of Notre Dame
4. Notre Dame
5. USA
Abstract
Amidophenoxide-to-osmium π donation is sensitive to the co-ligands; it engenders significant anisotropy in the bonding with an oxo group.
Funder
National Science Foundation
U.S. Department of Education
University of Notre Dame
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01735C
Reference34 articles.
1. Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism
2. Redox activity and π bonding in a tripodal seven-coordinate molybdenum(vi) tris(amidophenolate)
3. Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity
4. o-Iminobenzosemiquinonato(1−) and o-Amidophenolato(2−) Complexes of Palladium(II) and Platinum(II): A Combined Experimental and Density Functional Theoretical Study
5. Highly covalent metal–ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium
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1. Slip to π Ru: structural distortions due to metal-iminoxolene π bonding;Chemical Communications;2023
2. Optically active bis(aminophenols) and their metal complexes;Dalton Transactions;2023
3. Slicing the π in Three Unequal Pieces: Iridium Complexes with Alkyne, Iminoxolene, and Dioxolene Ligands;Organometallics;2022-11-08
4. Mono- and Bis(iminoxolene)iridium Complexes: Synthesis and Covalency in π Bonding;Inorganic Chemistry;2022-03-31
5. Amphiphilicity in Oxygen Atom Transfer Reactions of Oxobis(iminoxolene)osmium Complexes;Inorganic Chemistry;2021-03-03
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