Two new members in the quaternary Cs–Ag–As–S family with different arrangements of Ag–S and As–S asymmetric building units: syntheses, structures, and theoretical studies

Author:

Yan Dongming1234,Xiao Yu56274,Liu Chang56274,Hou Peipei56274,Chai Wenxiang89104,Hosono Hideo11121314,Lin Hua151617184ORCID,Liu Yi56274ORCID

Affiliation:

1. School of Civil and Architectural Engineering

2. Zhejiang University

3. Hangzhou 310058

4. China

5. Institute for Composites Science Innovation (InCSI)

6. School of Materials Science and Engineering

7. Hangzhou 310027

8. College of Materials Science and Engineering

9. China Jiliang University

10. Hangzhou 310018

11. Materials Research Center for Element Strategy

12. Tokyo Institute of Technology

13. Yokohama 226-8503

14. Japan

15. State Key Laboratory of Structural Chemistry

16. Fujian Institute of Research on the Structure of Matter

17. Chinese Academy of Sciences

18. Fuzhou 350002

Abstract

Two novel quaternary layered thioarsenates(iii), Cs2Ag2As2S5 (I) and Cs3AgAs4S8 (II), with different arrangements of Ag–S and As–S asymmetric building units are reported.

Funder

National Basic Research Program of China

National Natural Science Foundation of China

Natural Science Foundation of Fujian Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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