Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion-Reference-Cited by-同舟云学术

Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion

Published:2018 Issue:66 Volume:54 Page:9159-9162
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Faulkner Robert A.¹²³⁴⁵^ORCID,Patmore Nathan J.¹²³⁴⁵^ORCID,Rice Craig R.¹²³⁴⁵^ORCID,Slater Christopher¹²³⁴⁵

Affiliation:

1. Department of Chemical Sciences

2. School of Applied Sciences

3. University of Huddersfield

4. Huddersfield HD1 3DH

5. UK

Abstract

Ligands L1 and L2 both form dinuclear assemblies with Cu(ii) and these react with dihydrogen phosphate to give [Cu₂L₂(H₂PO₄)]³⁺. However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu₃(L1)₃(O₃POBF₃)]³⁺ and [Cu₂(L²)₂(O₂P(OBF₃)₂)]⁺.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC04900A

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